Catalizadores de níquel y paladio con ligandos carbeno N-heterocíclicos para la formación de enlaces C-C y C-N
- GONZÁLEZ RULL, SILVIA
- Manuel Romero Fructos-Vázquez Directeur
- Tomás Rodríguez Belderraín Directeur
Université de défendre: Universidad de Huelva
Fecha de defensa: 15 juin 2017
- José Luis Mascareñas Cid President
- Ana Carmen Albéniz Jiménez Secrétaire
- Beatriz Royo Cantabrana Rapporteur
Type: Thèses
Résumé
This PhD Thesis is divided in three Chapters. Two of them are focused on the use of nickel and palladium complexes with N-heterocyclic carbene ligands (NHC) and phosphine-functionalized N-heterocyclic carbene ligands (NHCP), in the cross-coupling reactions to form C~C and C-N bonds. The third Chapter describes the cyclopropanation reaction of styrene with different diazocompounds catalyzed by nickel and palladium complexes with NHCP ligands.