Patrones de tierras raras y estudio isotópico preliminar del caolín asociado a un paleosuelo laterítico del suroeste peninsular
- J.C. Fernández-Caliani 1
- M. Cantano 1
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1
Universidad de Huelva
info
ISSN: 1576-5172
Year of publication: 2016
Issue Title: IX CONGRESO GEOLÓGICO DE ESPAÑA
Issue: 16
Pages: 391-394
Type: Article
More publications in: Geotemas (Madrid)
Abstract
This study reports the concentrations and fractionation patterns of rare-earth elements (REE) in a lateritic paleosol developed on arkosic sands (Bonares Sands Formation) since the Late Pliocene in South-West Spain, and it explores the stable isotope signature of the kaolin in order to constrain the paleoweathering event. The kaolinized material appears to be markedly impoverished in REE, showing relatively flat patterns with little fractionation (LaN/LuN<2) and irrelevant europium anomalies (Eu/Eu*=0.8-1.3). The isotope composition of the kaolinite (δ18O=17.3‰ and δD=-65‰) is consistent with a supergene origin. Kaolin was formed in equilibrium with meteoric waters under (sub)tropical weathering conditions.