Publications in collaboration with researchers from Heriot-Watt University (10)

2022

  1. Inverse Isotope Effects in Single-Crystal to Single-Crystal Reactivity and the Isolation of a Rhodium Cyclooctane σ-Alkane Complex

    Organometallics, Vol. 41, Núm. 3, pp. 284-292

2021

  1. A Series of Crystallographically Characterized Linear and Branched σ-Alkane Complexes of Rhodium: From Propane to 3-Methylpentane

    Journal of the American Chemical Society, Vol. 143, Núm. 13, pp. 5106-5120

  2. Ortho-aryl substituted DPEphos ligands: rhodium complexes featuring C-H anagostic interactions and B-H agostic bonds

    Chemical Science, Vol. 12, Núm. 25, pp. 8832-8843

2020

  1. A Structurally Characterized Cobalt(I) σ-Alkane Complex

    Angewandte Chemie - International Edition, Vol. 59, Núm. 15, pp. 6177-6181

2019

  1. A d10 Ag(i) amine-borane σ-complex and comparison with a d8 Rh(i) analogue: Structures on the η1 to η2:η2 continuum

    Dalton Transactions, Vol. 48, Núm. 26, pp. 9776-9781

  2. Room Temperature Acceptorless Alkane Dehydrogenation from Molecular σ-Alkane Complexes

    Journal of the American Chemical Society, Vol. 141, Núm. 29, pp. 11700-11712

  3. The role of neutral Rh(PONOP)H, free NMe2H, boronium and ammonium salts in the dehydrocoupling of dimethylamine-borane using the cationic pincer [Rh(PONOP)(η2-H2)]+ catalyst

    Dalton Transactions, Vol. 48, Núm. 39, pp. 14724-14736

2018

  1. Controlling Structure and Reactivity in Cationic Solid-State Molecular Organometallic Systems Using Anion Templating

    Organometallics, Vol. 37, Núm. 20, pp. 3524-3532

  2. Modulation of σ-Alkane Interactions in [Rh(L2)(alkane)]+ Solid-State Molecular Organometallic (SMOM) Systems by Variation of the Chelating Phosphine and Alkane: Access to η2,η2-σ-Alkane Rh(I), η1-σ-Alkane Rh(III) Complexes, and Alkane Encapsulation

    Journal of the American Chemical Society, Vol. 140, Núm. 44, pp. 14958-14970

2017

  1. Solid-state molecular organometallic chemistry. Single-crystal to single-crystal reactivity and catalysis with light hydrocarbon substrates

    Chemical Science, Vol. 8, Núm. 9, pp. 6014-6029